- Right click on the dock > Layouts > Configure...
- In Settings window, go to Preferences tab
- In Actions section > Tick Press ⌘ to activate Application Launcher

Or
-
Open ~/.config/kwinrc, then add:
... [ModifierOnlyShortcuts] Meta=org.kde.lattedock,/Latte,org.kde.LatteDock,activateLauncherMenu ... -
Reload KWin:
$ qdbus org.kde.KWin /KWin reconfigure
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